Mechanical Properties and Hydrogen Embrittlement of Laser-Surface Melted AISI 430 Ferritic Stainless Steel

In the present study, the feasibility of laser surface melting (LSM) of AISI 430 ferritic stainless steel to minimize hydrogen embrittlement (HE) was investigated. LSM of AISI 430 steel was successfully achieved by a 2.3-kW high power diode laser (HPDL) with scanning speeds of 60 mm/s and 80 mm/s (the samples are designated as V60 and V80, respectively) at a power of 2 kW. To investigate the HE effect on the AISI 430 steel without and with LSM, hydrogen was introduced into specimens by cathodic charging in 0.1 M NaOH solution under galvanostatic conditions at a current density of 30 mA/cm2 and 25 °C. Detail microstructural analysis was performed and the correlation of microstructure with HE was evaluated. By electron backscatter diffraction (EBSD) analysis, the austenite contents for the laser-surface melted specimens V60 and V80 are found to be 0.6 and 1.9 wt%, respectively. The amount of retained austenite in LSM specimens was reduced with lower laser scanning speed. The surface microhardness of the laser-surface melted AISI 430 steel (~280 HV0.2) is found to be increased by 56% as compared with that of the substrate (~180 HV0.2) because of the presence of martensite. The degree of embrittlement caused by hydrogen for the charged and non-charged AISI 430 steel was obtained using slow-strain-rate tensile (SSRT) test in air at a strain rate of 3 × 10−5 s−1. After hydrogen pre-charging, the ductility of as-received AISI 430 steel was reduced from 0.44 to 0.25 while the laser-surface melted AISI 430 steel showed similar tensile properties as the as-received one. After LSM, the value of HE susceptibility Iδ decreases from 43.2% to 38.9% and 38.2% for V60 and V80, respectively, due to the presence of martensite.


Introduction
Hydrogen is the most available renewable energy for its abundance. In addition, only water vapor is produced from hydrogen reaction. Thus, hydrogen energy is considered as the cleanest energy source [1]. Hydrogen energy is also recognized to be one of the most suitable solutions to the environmental problems nowadays if it is produced from renewable resources. Owing to excellent corrosion performance of stainless steels, they are widely used in power and nuclear plants as hydrogen storage vessels. During storage of hydrogen in metallic vessels, the most critical issues are the adsorption/desorption and permeation of hydrogen in the metallic materials, as well as possible hydrogen embrittlement (HE). In particular, ferritic and austenitic stainless steels and nickel-based alloys exhibit a minimum ductility at a specific temperature not far from room temperature. It is a serious problem for the use of these alloys as storage tank for fuel cells used in automotive applications [2][3][4][5][6]. In the present study, the feasibility of LSM of AISI 430 steel for minimizing HE was investigated. To study the HE effect on the AISI 430 steel without and with LSM, hydrogen was introduced into the specimens by cathodic charging under galvanostatic conditions by a DC power supply. The setup of hydrogen pre-charging of AISI 430 steel is shown in Figure 1a. A graphite electrode was connected to the positive lead of the power supply and the specimen was connected to the negative lead in the 0.1 M NaOH solution at 25 • C at a current density of 30 mA/cm 2 for one week. NaOH solution was used instead of H 2 SO 4 solution because of the more effective charging effect of the former as reported by Zakroczymsk [13]. LSM of AISI 430 steel was carried out using a 2.3-kW continuous wave (CW) HPDL with a power of 2 kW, a beam diameter of 2 mm, and various scanning speeds (60 and 80 mm/s). The specimens were designated as V60 and V80, respectively. The schematic diagram of the LSM setup of AISI 430 steel is shown in Figure 1b. Argon flowing at 15 L/min was used as the shielding gas. The lasersurface melted specimens were achieved by overlapping the parallel tracks with an overlapping degree of 50% (Figure 1c). A laser-surface melted specimen for hydrogen pre-charging and tensile testing is shown in Figure 1d. The investigation conditions of the samples for the present study are tabulated in Table 2: Table 2. Investigation conditions for AISI 430 steel: M stands for microstructural analysis, X stands for XRD analysis, H stands for microhardness test, T stands for tensile test, and F stands for fractography analysis. The laser-surface melted specimens were cross-sectioned, mechanically ground, polished, and then etched. The microstructure and phases of the specimens were analyzed using a field emission scanning-electron microscope (FESEM, Zeiss Zigma, Jena, Germany) equipped with an electron backscatter diffraction (EBSD, Oxford, Abingdon, U.K.) detector, and X-ray diffractometry (XRD, LSM of AISI 430 steel was carried out using a 2.3-kW continuous wave (CW) HPDL with a power of 2 kW, a beam diameter of 2 mm, and various scanning speeds (60 and 80 mm/s). The specimens were designated as V60 and V80, respectively. The schematic diagram of the LSM setup of AISI 430 steel is shown in Figure 1b. Argon flowing at 15 L/min was used as the shielding gas. The laser-surface melted specimens were achieved by overlapping the parallel tracks with an overlapping degree of 50% ( Figure 1c). A laser-surface melted specimen for hydrogen pre-charging and tensile testing is shown in Figure 1d. The investigation conditions of the samples for the present study are tabulated in Table 2: The laser-surface melted specimens were cross-sectioned, mechanically ground, polished, and then etched. The microstructure and phases of the specimens were analyzed using a field emission scanning-electron microscope (FESEM, Zeiss Zigma, Jena, Germany) equipped with an electron backscatter diffraction (EBSD, Oxford, Abingdon, U.K.) detector, and X-ray diffractometry (XRD, Rigaku MiniFlex 600, Tokyo, Japan). The radiation source of the XRD was Cu Kα with Ni filter and generated at 600 W. The scan rate used was 0.1 • /s. Microhardness measurements were conducted along the melt zones longitudinally using a Vickers hardness tester (VH3100, Buehler, Esslingen, Germany) with a load of 200 g and a loading time of 10 s. The degree of embrittlement caused by hydrogen for the laser-surface melted specimens without and with hydrogen pre-charging were assessed using slow-strain-rate tensile (SSRT) tests in air at a strain rate of 3 × 10 −5 s −1 at 25 • C according to ASTM standard G129-00 [14]. To investigate the HE susceptibility, the relative plastic loss I δ is defined as the HE susceptibility [15]: where I HC and I UC are the elongation of the hydrogen pre-charged and uncharged specimens, respectively. The fracture morphologies of the laser-surface melted and as-received specimens after the SSRT tests were studied by the FESEM. The investigation conditions of the samples without hydrogen pre-charging are shown in Table 2a. Three samples were tested for each set of measuring conditions for XRD analysis, tensile and microhardness testing (with error measurements) to ensure the repeatability of the results. One sample was selected for microstructural analysis and fractography analysis (both were studied using FESEM), while the investigation conditions for the samples with hydrogen pre-charging are shown in Table 2b. Three samples were taken for each set of measuring conditions for the tensile test and one sample was selected for fractography analysis using FESEM.

Microstructural Analysis
The cross-sections and microstructures of the laser-surface melted AISI 430 steel fabricated at different processing speeds (60 mm/s and 80 mm/s) under different magnifications are shown in Figure 2. The as-received AISI 430 steel contains a fully ferritic phase (confirmed by XRD as shown in Figure 3) with an average grain size of 15 µm. After LSM, the grain size of the ferrite in the melt zone (MZ) is considerably increased to 57 µm (V80) and to 67 µm (V60), while the grain size in the heat-affected zone (HAZ) is smaller (44 µm for V80 and 48 µm for V60). This structure of the ferrite has a polygonal morphology and the white phases at the grain boundaries are mainly martensite [ Figure 2a(ii),b(ii)]. A tiny amount of retained austenite was detected using EBSD (Table 3).
Compared with the laser-surface melted specimen at lower scanning speed (V60), a smaller grain size was observed for V80 (fabricated at higher scanning speed) as shown in Table 3. At a higher scanning speed (V80), the interaction time between the laser and the material was shorter leading to a higher quenching rate and hence a smaller grain size in the MZ. Grain size is expected to be controlled by applying high scanning speed (lower heat input) during LSM in order to keep the mechanical strength of AISI 430 steel.
The thickness and grain size of the MZ and HAZ for the laser-surface melted specimens decrease as the scanning speed increases ( Table 3). The thicknesses for V60 and V80 of the MZ are quite close. Conde and his co-workers reported that the austenite started to appear in the interdendritic region in form of Widmanstatten austenite platelets [12] as in V60 and V80. At higher laser scanning speed (V80), the volume fraction of austenite is higher. Since the austenite is less prone to hydrogen diffusion [7,8], the presence of austenite in the laser-surface melted specimens may delay the hydrogen diffusion. From Figure 2a(i),b(i), a narrow HAZ can be observed in which fewer martensites are present along ferrite grain boundaries.
For investigating the cooling effects on the stainless steels, the primary solidification mode was determined by the modified Schaeffter diagram [16]. The chromium equivalent (Cr eq ) and nickel equivalent (Ni eq ) [17] are defined below: Coatings 2020, 10, 140 5 of 16 Since the Cr eq /Ni eq ratio of AISI 430 steel is high (16.436/3.845 = 4.27), the formation tendency of δ-ferrite is very high. Through a primary ferrite solidification mode, the laser-surface melted AISI 430 steel mainly possesses columnar grains of primary δ-ferrite [ Figure 2a] with a small amount of intergranular martensite (α')/austenite (γ) formed at boundaries of δ grains as the minor phases ( Figure 2a(ii),b(ii)). From the pseudo-binary phase diagram of Fe-C at 17% Cr [18], a major ferritic microstructure can be achieved by suppressing the austenite formation at elevated temperatures. As the melt pools of the laser-melted specimens solidify, the sequence of phase transformation upon cooling is the primary solidification of δ: After LSM, δ-ferrite is the first phase to solidify followed by partial transformation from δ-ferrite to austenite during cooling. Under a non-equilibrium cooling condition (i.e., LSM), martensite was formed at the grain boundaries by solid-state transformation of austenite [18]. It is reported that the microstructure of AISI 430 steel is significantly affected by the laser processing conditions (i.e., scanning speed and power density); hence, the cooling rate [12]. Similar microstructures (primary δ with a small amount of intergranular martensite) were observed in AISI 430 steel [16].
Martensite was detected at the grain boundaries of the ferritic grains. The martensite formation in the melt zone of laser-surface melted AISI 430 steel can be predicted from the chemical compositions using the Kaltenhauser ferrite factor (KFF) [19]: It is reported that the formation of martensite during the welding of FSS can be avoided if its KFF factor is larger than 17 [18]. In the present study, the KFF of AISI 430 steel was calculated to be 11.7. Martensite was observed in the melt zone of the laser-surface melted specimens ( Figure 2). However, the KFF did not reflect the martensite content in the laser-surface melted specimens. Thus, the Balmforth diagram was used to predict the microstructure of the laser-surface melted AISI 430 steel [18,20]. From Figure 2a(ii),b(ii), the major columnar δ-ferritic structure with a small amount of martensite (4.8%-5.4%) and austenite (less than 2%) can be observed. It is in accordance with the prediction using the Balmforth diagram.
The XRD patterns of the as-received and laser-surface melted specimens are shown in Figure 3. From Figure 3a, only α-ferrite was detected in the as-received AISI 430 steel. The peaks for δ-ferrite and martensite in the laser-surface melted specimens are overlapped and cannot be distinguished. For V60, the main phase detected was δ-ferrite/martensite and a very small peak of austenite (γ) was detected at 50.7 • (Figure 3b). For V80, more significant austenite peaks were detected at 43.5 • and 50.7 • due to the higher processing speed (Figure 3c). The existence of austenite depicted in the XRD patterns was consistent with the austenite detected using EBSD. From the EBSD results, a small amount of austenite can be observed in the laser-surface melted specimens. The corresponding austenite contents for V60 and V80 are found to be 0.6 and 1.9 wt%, respectively. At a higher laser processing speed, the quenching rate is higher, the time for austenite-ferrite transformation decreased, and the volume fraction of retained austenite increases. The result is supported by Conde et al. [12] and Colacë and Vilar [21]. From Conde and his co-workers' research [12], it was reported that the retained austenite increased as the laser scanning speed increased. From Colacë and Vilar's research [21], the amount of retained austenite in the laser-surface melted FSS was reduced by decreasing the laser scanning speed and increasing the laser power density. Their studies are consistent with the present EBSD results.

Microhardness
The microhardness profiles along the cross-section of the laser-surface melted specimens V60 and V80 are shown in Figure 4. The width of the MZ is about 250 μm, the microhardness is in the range of 270-290 HV0.2. Despite the larger grain size, the laser-surface melted AISI 430 steel (V60 and V80) has a significant increase in microhardness owing to the formation of martensite. This result is supported by Sundqvist and his co-workers [22]. Compared with the substrate, the MZ microhardness of the laser-surface melted specimens is increased by 56%. Compared with V60, lower microhardness was found at the MZ for V80 due to higher austenite content. The result is also supported by Khorram and his co-workers [23], who reported that the increase in martensite content (i.e., decrease in retained austenite content) causes the increase in microhardness value.
In the HAZ, at the depth ranging from 250 to 500 μm, the microhardness is about 220 HV0.2 and lower than that of the MZ, but it is still higher than the substrate (180 HV0.2). It is attributed to the partial transformation into martensite leading to intermediate microhardness. No notable softening from tempering by subsequent laser irradiation was found.

Microhardness
The microhardness profiles along the cross-section of the laser-surface melted specimens V60 and V80 are shown in Figure 4. The width of the MZ is about 250 µm, the microhardness is in the range of 270-290 HV 0.2 . Despite the larger grain size, the laser-surface melted AISI 430 steel (V60 and V80) has a significant increase in microhardness owing to the formation of martensite. This result is supported by Sundqvist and his co-workers [22]. Compared with the substrate, the MZ microhardness of the laser-surface melted specimens is increased by 56%. Compared with V60, lower microhardness was found at the MZ for V80 due to higher austenite content. The result is also supported by Khorram and his co-workers [23], who reported that the increase in martensite content (i.e., decrease in retained austenite content) causes the increase in microhardness value.
In the HAZ, at the depth ranging from 250 to 500 µm, the microhardness is about 220 HV 0.2 and lower than that of the MZ, but it is still higher than the substrate (180 HV 0.2 ). It is attributed to the partial transformation into martensite leading to intermediate microhardness. No notable softening from tempering by subsequent laser irradiation was found.

Tensile Properties
The engineering stress vs. engineering strain curves for the as-received AISI 430 steel and lasersurface melted AISI 430 steel (V60 and V80) without and with hydrogen pre-charging are shown in Figure 5, and the corresponding mechanical parameters are tabulated in Table 4. Compared with the as-received AISI 430 steel, the yield strength of the laser-surface melted AISI 430 steel is similar and the tensile strength is increased by 8.6%-11.5%, while the ductility is significantly reduced from 0.44 to 0.34-0.36 (decrease by 20%).
The ductility (strain to failure) of the as-received AISI 430 steel after hydrogen pre-charging was dramatically decreased from 0.44 to 0.25 (decreased by 43%). The reason for the severe embrittlement is due to the high diffusivity of hydrogen atom in the α-ferrite [24]. On the other hand, the tensile strength and ductility of the laser-surface melted AISI 430 steel after hydrogen pre-charging is reduced but the yield strength is similar as compared to the laser-surface melted AISI 430 steel without hydrogen pre-charging.

Tensile Properties
The engineering stress vs. engineering strain curves for the as-received AISI 430 steel and laser-surface melted AISI 430 steel (V60 and V80) without and with hydrogen pre-charging are shown in Figure 5, and the corresponding mechanical parameters are tabulated in Table 4. Compared with the as-received AISI 430 steel, the yield strength of the laser-surface melted AISI 430 steel is similar and the tensile strength is increased by 8.6%-11.5%, while the ductility is significantly reduced from 0.44 to 0.34-0.36 (decrease by 20%).
The ductility (strain to failure) of the as-received AISI 430 steel after hydrogen pre-charging was dramatically decreased from 0.44 to 0.25 (decreased by 43%). The reason for the severe embrittlement is due to the high diffusivity of hydrogen atom in the α-ferrite [24]. On the other hand, the tensile strength and ductility of the laser-surface melted AISI 430 steel after hydrogen pre-charging is reduced but the yield strength is similar as compared to the laser-surface melted AISI 430 steel without hydrogen pre-charging.
Increase in tensile strength for the laser-surface melted AISI 430 steel is due to strengthening via heating with the laser beam followed by rapid quenching leading to a formation of martensite.
The corresponding values of I δ for the as-received AISI 430 steel, V60 and V80, are tabulated in Table 4. A higher value of I δ indicates a higher plastic loss after hydrogen charging, i.e., the as-received AISI 430 steel is more susceptible to HE. After LSM, the value of I δ decreases from 43.2% to 38.9% and 38.2% for V60 and V80, respectively. From the EBSD results, the austenite contents of V60 and V80 are 0.6% and 1.9%, respectively. As the content of austenite in the laser-surface melted AISI 430 steel is very low, the presence of austenite for reducing the hydrogen diffusion causes a minor effect on the HE susceptibility. A smaller I δ value is obtained due to the presence of martensite, which is more susceptible to HE as compared to ferrite [25,26]. Table 4 compares the yield strength, tensile strength, ductility, and HE susceptibility (I δ ) for all samples. In the present study, the laser-surface melted specimens (V60 and V80) possessed higher microhardness ( Figure 4) and lower HE susceptibility ( Table 4) than those of the as-received AISI 430 steel. The decrease in HE susceptibility with microhardness was consistent with the finding of Sebastián et al. [27].
Coatings 2020, 10, x FOR PEER REVIEW 11 of 16 Increase in tensile strength for the laser-surface melted AISI 430 steel is due to strengthening via heating with the laser beam followed by rapid quenching leading to a formation of martensite. The corresponding values of Iδ for the as-received AISI 430 steel, V60 and V80, are tabulated in Table 4. A higher value of Iδ indicates a higher plastic loss after hydrogen charging, i.e., the as-received AISI 430 steel is more susceptible to HE. After LSM, the value of Iδ decreases from 43.2% to 38.9% and 38.2% for V60 and V80, respectively. From the EBSD results, the austenite contents of V60 and V80 are 0.6% and 1.9%, respectively. As the content of austenite in the laser-surface melted AISI 430 steel is very low, the presence of austenite for reducing the hydrogen diffusion causes a minor effect on the HE susceptibility. A smaller Iδ value is obtained due to the presence of martensite, which is more susceptible to HE as compared to ferrite [25,26]. Table 4 compares the yield strength, tensile strength, ductility, and HE susceptibility (Iδ) for all samples. In the present study, the laser-surface melted specimens (V60 and V80) possessed higher microhardness ( Figure 4) and lower HE susceptibility ( Table 4) than those of the as-received AISI 430 steel. The decrease in HE susceptibility with microhardness was consistent with the finding of Sebastián et al. [27].

Fractography
The fracture morphologies of the as-received AISI 430 steel without and with hydrogen precharging after tensile test are shown in Figure 6. Ductile fracture was observed for both specimens,

Fractography
The fracture morphologies of the as-received AISI 430 steel without and with hydrogen pre-charging after tensile test are shown in Figure 6. Ductile fracture was observed for both specimens, although the ductility of the as-received AISI 430 steel was dropped after hydrogen pre-charging. Large microvoids or dimples on the fracture surface are observed and are the characteristics of the Hydrogen Enhanced Localized Plasticity (HELP) mechanism [28]. According to the plasticity model 'Hydrogen Enhanced Localized Plasticity (HELP)', which was first established by Beachem [29], the presence of hydrogen in the ferrite increases the mobility of dislocations and creates hydrogen-induced strain localizations. The hydrogen effect is the greatest at the crack tip where the local hydrogen concentration is increased by the effect of stress concentration. Hydrogen locally softens the material in front of the crack tip allowing ductile fracture to occur there, prior to general yielding in the bulk of material, away from the crack tip. When the crack initiates and propagates further, the stress concentration at the crack tip will increase [30]. When the crack tip meets the pile-up dislocation sites, brittle fracture will occur. At the microscopic level, plasticity is enhanced by hydrogen. On the other hand, at the macroscopic level, the material exhibits a brittle behavior [31]. The present result on HE is also supported by Malitckii and his co-workers [32], who reported that hydrogen led to significant plastic strain localization in the vicinity of the crack tips, and slip bands formed associated with deformation structures also followed the HELP mechanism.
Coatings 2020, 10, x FOR PEER REVIEW 12 of 16 although the ductility of the as-received AISI 430 steel was dropped after hydrogen pre-charging. Large microvoids or dimples on the fracture surface are observed and are the characteristics of the Hydrogen Enhanced Localized Plasticity (HELP) mechanism [28]. According to the plasticity model 'Hydrogen Enhanced Localized Plasticity (HELP)', which was first established by Beachem [29], the presence of hydrogen in the ferrite increases the mobility of dislocations and creates hydrogeninduced strain localizations. The hydrogen effect is the greatest at the crack tip where the local hydrogen concentration is increased by the effect of stress concentration. Hydrogen locally softens the material in front of the crack tip allowing ductile fracture to occur there, prior to general yielding in the bulk of material, away from the crack tip. When the crack initiates and propagates further, the stress concentration at the crack tip will increase [30]. When the crack tip meets the pile-up dislocation sites, brittle fracture will occur. At the microscopic level, plasticity is enhanced by hydrogen. On the other hand, at the macroscopic level, the material exhibits a brittle behavior [31]. The present result on HE is also supported by Malitckii and his co-workers [32], who reported that hydrogen led to significant plastic strain localization in the vicinity of the crack tips, and slip bands formed associated with deformation structures also followed the HELP mechanism.
(a) (b) With the presence of martensite, the HE susceptibility of V60 and V80 decreases [15,33]. The main fracture mode was a mixture of intergranular and quasi-cleavage fracture. This is in agreement with the observation of an intergranular phase (α' and γ) in the laser-surface melted specimens [ Figure 2a(iii),b(iii)]. The existence of martensite is the most plausible explanation for the low toughness observed in such specimens. From Figure 7b(ii), the regions with very small microvoids correspond to the ferrite grains, while the narrow-stripe regions consist of martensite. Figure 8b(ii) shows similar fracture morphology as Figure 7b(ii), which is the MZ of V80. From Figure  7b(iii), a mixture of ductile and brittle fracture modes can be observed in the substrate, with the presence of cleavage (inside red box) and small dimples. The dimples are typically the HELP mechanism, where the size of the dimples is smaller after hydrogen charging compared to as-received AISI 430 steel. The cleavage area is slightly smaller in Figure 8b(iii) compared with Figure 7b(iii), and the dimples are larger compared with Figure 7b(iii). The main reason is due to the more austenites formed in V60 and in V80 that reduce the effect of hydrogen embrittlement. The effect of LSM on fracture morphology dominates over the effect of hydrogen pre-charging for both V60 and V80. With the presence of martensite, the HE susceptibility of V60 and V80 decreases [15,33]. The main fracture mode was a mixture of intergranular and quasi-cleavage fracture. This is in agreement with the observation of an intergranular phase (α' and γ) in the laser-surface melted specimens [ Figure 2a(iii),b(iii)]. The existence of martensite is the most plausible explanation for the low toughness observed in such specimens. From Figure 7b(ii), the regions with very small microvoids correspond to the ferrite grains, while the narrow-stripe regions consist of martensite. Figure 8b(ii) shows similar fracture morphology as Figure 7b(ii), which is the MZ of V80. From Figure 7b(iii), a mixture of ductile and brittle fracture modes can be observed in the substrate, with the presence of cleavage (inside red box) and small dimples. The dimples are typically the HELP mechanism, where the size of the dimples is smaller after hydrogen charging compared to as-received AISI 430 steel. The cleavage area is slightly smaller in Figure 8b(iii) compared with Figure 7b(iii), and the dimples are larger compared with Figure 7b(iii). The main reason is due to the more austenites formed in V60 and in V80 that reduce the effect of hydrogen embrittlement. The effect of LSM on fracture morphology dominates over the effect of hydrogen pre-charging for both V60 and V80. Coatings 2020, 10, x FOR PEER REVIEW 13 of 16

Conclusions
• The austenite contents for the laser-surface melted samples V60 and V80 are found to be 0.6 and 1.9 wt%, respectively. The amount of retained austenite reduces as the laser scanning speed decreases; • At higher laser scanning speed, the quenching rate is higher resulting in more austenite. The microhardness at MZ and HAZ of laser-surface melted samples is about 270-280 HV0.2 and 220 HV0.2, respectively. Lower microhardness in V80 is due to a higher austenite content; • After hydrogen pre-charging, the ductility of as-received AISI 430 steel was reduced from 0.44 to 0.25, while the laser-surface melted AISI 430 steel showed similar tensile properties as the asreceived one. After LSM, the value of hydrogen embrittlement susceptibility I decreases from 43.2% to 38.9% and 38.2% for V60 and V80, respectively, due to the presence of martensite. The hydrogen embrittlement susceptibilities of both V60 and V80 decrease due to the presence of martensite; • Brittle fracture is observed in the melt zone of the laser-surface melted AISI 430 steel, while ductile fracture is observed in the as-received AISI 430 steel. After LSM, the main fracture mode changes from intergranular to a mixture of intergranular and quasi-cleavage fracture. The austenite formed in V60 and V80 can lessen the effect of hydrogen embrittlement. The effect of LSM dominates over the effect of hydrogen pre-charging on fracture morphologies.

Conclusions
• The austenite contents for the laser-surface melted samples V60 and V80 are found to be 0.6 and 1.9 wt%, respectively. The amount of retained austenite reduces as the laser scanning speed decreases; • At higher laser scanning speed, the quenching rate is higher resulting in more austenite. The microhardness at MZ and HAZ of laser-surface melted samples is about 270-280 HV 0.2 and 220 HV 0.2 , respectively. Lower microhardness in V80 is due to a higher austenite content; • After hydrogen pre-charging, the ductility of as-received AISI 430 steel was reduced from 0.44 to 0.25, while the laser-surface melted AISI 430 steel showed similar tensile properties as the as-received one. After LSM, the value of hydrogen embrittlement susceptibility I δ decreases from 43.2% to 38.9% and 38.2% for V60 and V80, respectively, due to the presence of martensite. The hydrogen embrittlement susceptibilities of both V60 and V80 decrease due to the presence of martensite; • Brittle fracture is observed in the melt zone of the laser-surface melted AISI 430 steel, while ductile fracture is observed in the as-received AISI 430 steel. After LSM, the main fracture mode changes from intergranular to a mixture of intergranular and quasi-cleavage fracture. The austenite formed in V60 and V80 can lessen the effect of hydrogen embrittlement. The effect of LSM dominates over the effect of hydrogen pre-charging on fracture morphologies.